Monomer adsorption on equilateral triangular lattices with attractive first-neighbor interactions.

نویسندگان

  • Alain J Phares
  • David W Grumbine
  • Francis J Wunderlich
چکیده

We have recently studied a model of monomer adsorption on infinitely long equilateral triangular lattices with terraces of finite width M and nonperiodic boundaries. This study was restricted to the case of repulsive adsorbate-adsorbate first-neighbor interactions but included attractive, repulsive, and negligible second-neighbor interactions. The present work extends this study to the case of attractive first-neighbors, and the phases are determined, as before, with a confidence exceeding 10 significant figures. Phase diagrams are included for terrace widths M < or =11. Most of the occupational characteristics of the phases fit exact analytic expressions in M. The infinite-M limit of these expressions, combined with other analyses, provide the complete phase diagram for the infinite two-dimensional lattice. In addition to the empty and full coverage phases, there are three phases exhibiting stripe and cluster features that were not observed in the case of repulsive first-neighbors.

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عنوان ژورنال:
  • Langmuir : the ACS journal of surfaces and colloids

دوره 24 1  شماره 

صفحات  -

تاریخ انتشار 2008